5-Hydroxy-2-Methylfurfural from Sugar Beet Thick Juice: Kinetic and Modeling Studies
نویسندگان
چکیده
5-Hydroxy-2-methylfurfural (HMF) has a high derivatization potential and is considered the sleeping giant of biobased platform chemicals. It accessible by acid hydrolysis various carbohydrate-containing feeds, preferably those in fructose content. We here report detailed study on use thick juice, an intermediate sucrose (SUC)-rich stream sugar factory, pure SUC for synthesis HMF batch reactor setup [in presence water sulfuric (0.01 M) at 180 °C]. Distinct differences reactivity were found both related to impurities (i.e., organic acids salts) juice. To better understand effect juice impurities, model studies performed involving solution spiked with one (organic such as maleic range salts potassium, sodium, calcium, magnesium cations carbonates, chlorides, sulfates anions). The data successfully modeled using kinetic main reactions network. developed revealed that sulfate anions have major yield time required reach its optimum are likely cause between
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ژورنال
عنوان ژورنال: ACS Sustainable Chemistry & Engineering
سال: 2021
ISSN: ['2168-0485']
DOI: https://doi.org/10.1021/acssuschemeng.0c06579